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TITLE 18. ENVIRONMENTAL QUALITY

CHAPTER 11. DEPARTMENT OF ENVIRONMENTAL QUALITY
WATER QUALITY STANDARDS


Supp. 03-1

ARTICLE 1. WATER QUALITY STANDARDS FOR SURFACE WATERS

Article 1, consisting of Appendices A through C, repealed April 24, 1996 (Supp. 96-2).

Article 1, consisting of Section R18-11-103, reserved effective April 24, 1996 (Supp. 96-2).

Article 1, consisting of Sections R18-11-105 and R18-11-106, and Appendices A and B, adopted April 24, 1996 (Supp. 96-2).

Article 1, consisting of Sections R18-11-101 and R18-11-102, R18-11-104, R18-11-107 through R18-11-109, R18-11-111 through R18-11-113, R18-11-115, R18-11-117 and R18-11-118, R18-11-120 and R18-11-121, amended effective April 24, 1996 (Supp. 96-2).

Article 1, consisting of Sections R18-11-101 through R18-11-121 and Appendices A through C, adopted effective February 18, 1992 (Supp. 92-1).

Article 1, consisting of Section R18-11-101, repealed effective February 18, 1992 (Supp. 92-1).

Article 1 consisting of Section R9-21-101 renumbered as Article 1, Section R18-11-101 (Supp. 87-3).

Section

R18-11-101. Definitions

R18-11-102. Applicability

R18-11-103. Repealed

R18-11-104. Designated Uses

R18-11-105. Tributaries; Designated Uses

R18-11-106. Net Ecological Benefit

R18-11-107. Antidegradation

R18-11-108. Narrative Water Quality Standards

R18-11-109. Numeric Water Quality Standards

R18-11-110. Salinity Standards for the Colorado River

R18-11-111. Analytical Methods

R18-11-112. Unique Waters

R18-11-113. Effluent-dependent Waters

R18-11-114. Mixing Zones

R18-11-115. Repealed

R18-11-116. Resource Management Agencies

R18-11-117. Canals and Municipal Park Lakes

R18-11-118. Dams and Flood Control Structures

R18-11-119. Natural Background

R18-11-120. Enforcement

R18-11-121. Schedules of Compliance

R18-11-122. Variances

R18-11-123. Prohibition Against Discharge

Appendix A. Numeric Water Quality Criteria

Appendix B. List of Surface Waters and Designated Uses

Appendix C. Repealed

ARTICLE 2. REPEALED

Article 2, consisting of Sections R18-11-201 through R18-11-205, adopted effective February 18, 1992 (Supp. 92-1).

Article 2, consisting of Sections R18-11-201 through R18-11-214 and Appendices A and B, repealed effective February 18, 1992 (Supp. 92-1).

Article 2 consisting of Sections R9-21-201 through R9-21-214 and Appendices A and B renumbered as Article 2, Sections R18-11-201 through R18-11-214 and Appendices A and B (Supp. 87-3).

ARTICLE 3. RECLAIMED WATER QUALITY STANDARDS

Article 3, consisting of Sections R18-11-301 through R18-11-309 and Table A, adopted by final rulemaking at 7 A.A.R. 870, effective January 22, 2001 (Supp. 01-1).

Article 3 heading repealed effective April 24, 1996 (Supp. 96-2).

Article 3, consisting of Sections R18-11-301 through R18-11-304 repealed effective February 18, 1992 (Supp. 92-1).

Article 3 consisting of Sections R9-21-301 through R9-21-304 renumbered as Article 3, Sections R18-11-301 through R18-11-304 (Supp. 87-3).

Section

R18-11-301. Definitions

R18-11-302. Applicability

R18-11-303. Class A+ Reclaimed Water

R18-11-304. Class A Reclaimed Water

R18-11-305. Class B+ Reclaimed Water

R18-11-306. Class B Reclaimed Water

R18-11-307. Class C Reclaimed Water

R18-11-308. Industrial Reuse

R18-11-309. Reclaimed Water Quality Standards for an Unlisted Type of Direct Reuse

Table A. Minimum Reclaimed Water Quality Requirements for Direct Reuse

ARTICLE 4. AQUIFER WATER QUALITY STANDARDS

Section

R18-11-401. Definitions

R18-11-402. Repealed

R18-11-403. Analytical Methods

R18-11-404. Laboratories

R18-11-405. Narrative Aquifer Water Quality Standards

R18-11-406. Numeric Aquifer Water Quality Standards: Drinking Water Protected Use

R18-11-407. Aquifer Water Quality Standards in Reclassified Aquifers

R18-11-408. Petition for Adoption of a Numeric Aquifer Water Quality Standard

Appendix 1. Repealed

Appendix 2. Repealed

Appendix 3. Repealed

Appendix 4. Repealed

Appendix 5. Repealed

Appendix 6. Repealed

Appendix 7. Repealed

ARTICLE 5. AQUIFER BOUNDARY AND PROTECTED USE CLASSIFICATION

New Article 5 consisting of Sections R18-11-501 through R18-11-504 and Section R18-11-506 adopted effective October 22, 1987.

Section

R18-11-501. Definitions

R18-11-502. Aquifer boundaries

R18-11-503. Petition for reclassification

R18-11-504. Agency action on petition

R18-11-505. Public participation

R18-11-506. Rescission of reclassification

ARTICLE 6. IMPAIRED WATER IDENTIFICATION

Article 6, consisting of Sections R18-11-601 through R18-11-606, made by final rulemaking at 8 A.A.R. 3380, effective July 12, 2002 (Supp. 02-3).

Section

R18-11-601. Definitions

R18-11-602. Credible Data

R18-11-603. General Data Interpretation Requirements

R18-11-604. Types of Surface Waters Placed on the Planning List and 303(d) List

R18-11-605. Evaluating a Surface Water or Segment for Listing and Delisting

R18-11-606. TMDL Priority Criteria for 303(d) Listed Surface Waters or Segments

ARTICLE 1. WATER QUALITY STANDARDS FOR SURFACE WATERS

R18-11-101. Definitions

The terms of this Article have the following meanings:

1. "Acute toxicity" means toxicity involving a stimulus severe enough to induce a response rapidly. In aquatic toxicity tests, an effect observed in 96 hours or less is considered acute.

2. "AgI" means agricultural irrigation.

3. "AgL" means agricultural livestock watering.

4. "Agricultural irrigation" means the use of a surface water for the irrigation of crops.

5. "Agricultural livestock watering" means the use of a surface water as a supply of water for consumption by livestock.

6. "Annual mean" means the arithmetic mean of monthly values determined over a consecutive 12-month period, provided that monthly values are determined for at least three months. The monthly value is the arithmetic mean of all values determined in a calendar month.

7. "Aquatic and wildlife (cold water)" means the use of a surface water by animals, plants, or other cold-water organisms, generally occurring at elevations greater than 5000 feet, for habitation, growth, or propagation.

8. "Aquatic and wildlife (effluent-dependent water)" means the use of an effluent-dependent water by animals, plants, or other organisms for habitation, growth, or propagation.

9. "Aquatic and wildlife (ephemeral)" means the use of an ephemeral water by animals, plants, or other organisms, excluding fish, for habitation, growth, or propagation.

10. "Aquatic and wildlife (warm water)" means the use of a surface water by animals, plants, or other warm-water organisms, generally occurring at elevations less than 5000 feet, for habitation, growth, or propagation.

11. "A&Wc" means aquatic and wildlife (cold water).

12. "A&We" means aquatic and wildlife (ephemeral).

13. "A&Wedw" means aquatic and wildlife (effluent-dependent water).

14. "A&Ww" means aquatic and wildlife (warm water).

15. "Clean Water Act" means the Federal Water Pollution Control Act [33 U.S.C. 1251 to 1387].

16. "Criteria" means elements of water quality standards that are expressed as pollutant concentrations, levels, or narrative statements representing a water quality that supports a designated use.

17. "Designated use" means a use specified in Appendix B of this Article for a surface water.

18. "Domestic water source" means the use of a surface water as a potable water supply. Coagulation, sedimentation, filtration, disinfection, or other treatments may be necessary to yield a finished water suitable for human consumption.

19. "DWS" means domestic water source.

20. "EDW" means effluent-dependent water.

21. "Effluent-dependent water" means a surface water that consists of discharges of treated wastewater that is classified as an effluent-dependent water by the Director under R18-11-113. An effluent-dependent water is a surface water that, without the discharge of treated wastewater, would be an ephemeral water.

22. "Ephemeral water" means a surface water that has a channel that is at all times above the water table, and that flows only in direct response to precipitation.

23. "Existing use" means those uses actually attained in the waterbody on or after November 28, 1975, whether or not they are included in the water quality standards.

24. "FBC" means full-body contact.

25. "FC" means fish consumption.

26. "Fish consumption" means the use of a surface water by humans for harvesting aquatic organisms for consumption. Harvestable aquatic organisms include, but are not limited to, fish, clams, turtles, crayfish, and frogs.

27. "Full-body contact" means the use of a surface water for swimming or other recreational activity that causes the human body to come into direct contact with the water to the point of complete submergence. The use is such that ingestion of the water is likely and sensitive body organs, such as the eyes, ears, or nose, may be exposed to direct contact with the water.

28. "Geometric mean" means the nth root of the product of n items or values. The geometric mean is calculated using the following formula:

29. "Hardness" means the sum of the calcium and magnesium concentrations, expressed as calcium carbonate (CaCO 3 ) in milligrams per liter.

30. "Intermittent surface water" means a stream or reach of a stream that flows continuously only at certain times of the year, as when it receives water from a spring or from another surface source, such as melting snow.

31. "Mixing zone" means a prescribed area or volume of a surface water that is contiguous to a point source discharge where initial dilution of the discharge takes place.

32. "National Pollutant Discharge Elimination System" means the point source discharge permit program established by § 402 of the Clean Water Act [33 U.S.C. 1342].

33. "Ninetieth percentile" means the value that may not be exceeded by more than 10% of the observations in a consecutive 12 month period. A minimum of 10 samples, each taken at least 10 days apart, are required to determine a ninetieth percentile.

34. "NNS" means no numeric standard.

35. "Oil" means petroleum in any form, including but not limited to crude oil, gasoline, fuel oil, diesel oil, lubricating oil, or sludge.

36. "Partial-body contact" means the recreational use of a surface water that may cause the human body to come into direct contact with the water, but normally not to the point of complete submergence (for example, wading or boating). The use is such that ingestion of the water is not likely and sensitive body organs, such as the eyes, ears, or nose, will not normally be exposed to direct contact with the water.

37. "PBC" means partial-body contact.

38. "Perennial surface water" means a surface water that flows continuously throughout the year.

39. "Pollutant" means fluids, contaminants, toxic wastes, toxic pollutants, dredged spoil, solid waste, substances and chemicals, pesticides, herbicides, fertilizers and other agricultural chemicals, incinerator residue, sewage, garbage, sewage sludge, munitions, petroleum products, chemical wastes, biological materials, radioactive materials, heat, wrecked or discarded equipment, rock, sand, cellar dirt, and mining, industrial, municipal, and agricultural wastes or any other liquid, solid, gaseous, or hazardous substance.

40. "Practical quantitation limit" means the lowest level of quantitative measurement that can be reliably achieved during routine laboratory operations.

41. "Recreational uses" means the full-body contact and partial-body contact designated uses.

42. "Regional Administrator" means the Regional Administrator of Region IX of the U.S. Environmental Protection Agency.

43. "Surface water" means a water of the United States and includes the following:

a. A water that is currently used, was used in the past, or may be susceptible to use in interstate or foreign commerce;

b. An interstate water, including an interstate wetland;

c. All other waters, such as an intrastate lake, reservoir, natural pond, river, stream (including an intermittent or ephemeral stream), creek, wash, draw, mudflat, sandflat, wetland, slough, backwater, prairie pothole, wet meadow, or playa lake, the use, degradation, or destruction of which would affect or could affect interstate or foreign commerce, including any such water:

i. That is or could be used by interstate or foreign travelers for recreational or other purposes;

ii. From which fish or shellfish are or could be taken and sold in interstate or foreign commerce; or

iii. That is used or could be used for industrial purposes by industries in interstate or foreign commerce;

d. An impoundment of a surface water as defined by this definition;

e. A tributary of a surface water identified in subsections (a) through (d) of this definition; and

f. A wetland adjacent to a surface water identified in subsections (a) through (e) of this definition.

44. "Total nitrogen" means the sum of the concentrations of ammonia (NH 3 ), ammonium ion (NH 4 +), nitrite (NO 2 ), and nitrate (NO 3 ), and dissolved and particulate organic nitrogen expressed as elemental nitrogen.

45. "Total phosphorus" means all of the phosphorus present in a sample, regardless of form, as measured by a persulfate digestion procedure.

46. "Toxic" means a pollutant or combination of pollutants, that after discharge and upon exposure, ingestion, inhalation, or assimilation into an organism, either directly from the environment or indirectly by ingestion through food chains, may cause death, disease, behavioral abnormalities, cancer, genetic mutations, physiological malfunctions (including malfunctions in reproduction), or physical deformations in the organism or its offspring.

47. "Unique water" means a surface water that is classified as an outstanding state resource water by the Director under R18-11-112.

48. "Use attainability analysis" means a structured scientific assessment of the factors affecting the attainment of a designated use including physical, chemical, biological, and economic factors.

49. "Wetland" means an area that is inundated or saturated by surface or groundwater at a frequency and duration sufficient to support, and that under normal circumstances does support, a prevalence of vegetation typically adapted for life in saturated soil conditions. A wetland includes a swamp, marsh, bog, cienega, tinaja, and similar areas.

50. "Zone of passage" means a continuous water route of volume, cross-sectional area, and quality necessary to allow passage of free-swimming or drifting organisms with no acutely toxic effect produced on the organisms.

Historical Note

Former Section R9-21-101 repealed, new Section R9-21-101 adopted effective January 29, 1980 (Supp. 80-1). Amended effective April 17, 1984 (Supp. 84-2). Amended effective January 7, 1985 (Supp. 85-1). Amended by adding subsection (C) effective August 12, 1986 (Supp. 86-4). Former Section R9-21-101 renumbered without change as Section R18-11-101 (Supp. 87-3). Former Section R18-11-101 repealed, new Section R18-11-101 adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Deleted first definition to R18-11-101(32) "Navigable Water", previously printed in error
(Supp. 96-3). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1). Amended by final rulemaking at 9 A.A.R. 716, effective April 8, 2003 (Supp. 03-1).

R18-11-102. Applicability

A. The water quality standards prescribed in this Article apply to surface waters.

B. The water quality standards prescribed in this Article do not apply to the following:

1. A waste treatment system, including an impoundment, pond, lagoon, or constructed wetland that is a part of the waste treatment system.

2. A man-made surface impoundment and associated ditches and conveyances used in the extraction, beneficiation, or processing of metallic ores, including a pit, pregnant leach solution pond, raffinate pond, tailing impoundment, decant pond, pond or a sump in a mine pit associated with dewatering activity, pond holding water that has come into contact with a process or product and that is being held for recycling, spill or upset catchment pond, or pond used for onsite remediation, that is not a surface water or is located in an area that once was a surface water but no longer remains a surface water because it has been and remains legally converted.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-103. Repealed

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Repealed effective April 24, 1996 (Supp. 96-2).

R18-11-104. Designated Uses

A. The Director shall adopt or remove a designated use or subcategory of a designated use by rule.

B. Designated uses of a surface water may include full-body contact, partial-body contact, domestic water source, fish consumption, aquatic and wildlife (cold water), aquatic and wildlife (warm water), aquatic and wildlife (ephemeral), aquatic and wildlife (effluent-dependent water), agricultural irrigation, and agricultural livestock watering. The designated uses for specific surface waters are listed in Appendix B of this Article.

C. Numeric water quality criteria to maintain and protect water quality for the designated uses are prescribed in Appendix A, R18-11-109, R18-11-110, and R18-11-112. Narrative water quality standards to protect all surface waters are prescribed in R18-11-108.

D. If a surface water has more than one designated use listed in Appendix B, the most stringent water quality criterion applies.

E. The Director shall revise the designated uses of a surface water if water quality improvements result in a level of water quality that permits a use that is not currently listed as a designated use in Appendix B.

F. In designating uses of a surface water and in establishing water quality criteria to protect the designated uses, the Director shall take into consideration the applicable water quality standards for downstream surface waters and shall ensure that the water quality standards that are established for an upstream surface water also provide for the attainment and maintenance of the water quality standards of downstream surface waters.

G. A use attainability analysis shall be conducted prior to removal of a designated use or adoption of a subcategory of a designated use that requires less stringent water quality criteria.

H. The Director may remove a designated use or adopt a subcategory of a designated use that requires less stringent water quality criteria, provided the designated use is not an existing use and it is demonstrated through a use attainability analysis that attaining the designated use is not feasible for any of the following reasons:

1. A naturally-occurring pollutant concentration prevents the attainment of the use;

2. A natural, ephemeral, intermittent, or low-flow condition or water level prevents the attainment of the use;

3. A human-caused condition or source of pollution prevents the attainment of the use and cannot be remedied or would cause more environmental damage to correct than to leave in place;

4. A dam, diversion, or other type of hydrologic modification precludes the attainment of the use, and it is not feasible to restore the surface water to its original condition or to operate the modification in a way that would result in attainment of the use;

5. A physical condition related to the natural features of the surface water, such as the lack of a proper substrate, cover, flow, depth, pools, riffles, and the like, unrelated to water quality, precludes attainment of an aquatic life designated use; or

6. Controls more stringent than those required by § 301 (b) and § 306 of the Clean Water Act [33 U.S.C. § 1311 and § 1316] are necessary to attain the use and implementation of the controls would result in substantial and widespread economic and social impact.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-105. Tributaries; Designated Uses

The following water quality standards apply to a surface water that is not listed in Appendix B but that is a tributary to a listed surface water.

1. The aquatic and wildlife (ephemeral) and partial-body contact standards apply to an unlisted tributary that is an ephemeral water.

2. The aquatic and wildlife (cold water), full-body contact, and fish consumption standards apply to an unlisted tributary that is a perennial or intermittent surface water and is above 5000 feet in elevation.

3. The aquatic and wildlife (warm water), full-body contact, and fish consumption standards apply to an unlisted tributary that is a perennial or intermittent surface water and is below 5000 feet in elevation.

Historical Note

Adopted effective April 24, 1996 (Supp. 96-2). Section heading amended per instructions of the Department of Environmental Quality, August 9, 1996 (Supp. 96-3). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-106. Net Ecological Benefit

A. The Director may, by rule, modify a water quality standard on the ground that there is a net ecological benefit associated with the discharge of effluent to support or create a riparian and aquatic habitat in an area where water resources are limited. The Director may modify a water quality standard for a pollutant if it is demonstrated that:

1. The discharge of effluent creates or supports an ecologically valuable aquatic, wetland, or riparian ecosystem in an area where these resources are limited;

2. The ecological benefits associated with the discharge of effluent under a modified water quality standard exceed the environmental costs associated with the elimination of the discharge of effluent;

3. The cost of treatment to achieve compliance with a water quality standard is so high that it is more cost effective to eliminate the discharge of effluent to the surface water. The discharger shall demonstrate that it is feasible to eliminate the discharge of effluent that creates or supports the ecologically valuable aquatic, wetland, or riparian ecosystem and that a plan to eliminate the discharge is under active consideration;

4. The discharge of effluent to the surface water will not cause or contribute to a violation of a water quality standard that has been established for a downstream surface water;

5. All practicable point source discharge control programs, including local pretreatment, waste minimization, and source reduction programs are implemented; and

6. The discharge of effluent does not produce or contribute to the concentration of a pollutant in the tissues of aquatic organisms or wildlife that is likely to be harmful to humans or wildlife through food chain concentration.

B. The Director shall not modify a water quality criterion for a pollutant to be less stringent than a technology-based effluent limitation that applies to the discharge of that effluent. The discharge of effluent shall, at a minimum, comply with applicable technology-based effluent limitations.

Historical Note

Adopted effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-107. Antidegradation

A. The Director shall determine whether there is degradation of water quality in a surface water on a pollutant-by-pollutant basis.

B. Tier 1: The level of water quality necessary to protect existing uses shall be maintained and protected. No degradation of existing water quality is permitted in a surface water where the existing water quality does not meet the applicable water quality standard.

C. Tier 2: Where existing water quality in a surface water is better than the applicable water quality standard, the existing water quality shall be maintained and protected. The Director may allow limited degradation of existing water quality in the surface water, provided that the Department holds a public hearing on whether degradation should be allowed under the general public hearing procedures prescribed at R18-1-401 and R18-1-402 and the Director makes all of the following findings:

1. The level of water quality necessary to protect existing uses is fully protected. Water quality shall not be lowered to a level that does not comply with applicable water quality standards.

2. The highest statutory and regulatory requirements for new and existing point sources are achieved.

3. All cost-effective and reasonable best management practices for nonpoint source pollution control are implemented.

4. Allowing lower water quality is necessary to accommodate important economic or social development in the area where the surface water is located.

D. Tier 3: Existing water quality shall be maintained and protected in a surface water that is classified as a unique water under R18-11-112. The Director shall not allow limited degradation of a unique water under subsection (C).

E. The Department shall implement this Section in a manner consistent with § 316 of the Clean Water Act [33 U.S.C. § 1326] if a potential water quality impairment associated with a thermal discharge is involved.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-108. Narrative Water Quality Standards

A. A surface water shall be free from pollutants in amounts or combinations that:

1. Settle to form bottom deposits that inhibit or prohibit the habitation, growth, or propagation of aquatic life;

2. Cause objectionable odor in the area in which the surface water is located;

3. Cause off-taste or odor in drinking water;

4. Cause off-flavor in aquatic organisms;

5. Are toxic to humans, animals, plants, or other organisms;

6. Cause the growth of algae or aquatic plants that inhibit or prohibit the habitation, growth, or propagation of other aquatic life or that impair recreational uses;

7. Cause or contribute to a violation of an aquifer water quality standard prescribed in R18-11-405 or R18-11-406; or

8. Change the color of the surface water from natural background levels of color.

B. A surface water shall be free from oil, grease, and other pollutants that float as debris, foam, or scum; or that cause a film or iridescent appearance on the surface of the water; or that cause a deposit on a shoreline, bank, or aquatic vegetation. The discharge of lubricating oil or gasoline associated with the normal operation of a recreational watercraft is not a violation of this narrative standard.

C. A discharge of suspended solids to a surface water shall not be in quantities or concentrations that either interfere with the treatment processes at the nearest downstream potable water treatment plant or substantially increase the cost of handling solids produced at the nearest downstream potable water treatment plant.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-109. Numeric Water Quality Standards

A. The following water quality standards for Escherichia coli (E. coli), expressed in colony forming units per 100 milliliters of water (cfu / 100 ml), shall not be exceeded:

E. coli FBC PBC

Geometric mean (four-sample minimum) 126 126

Single sample maximum 235 576

B. The following water quality standards for pH, expressed in standard units, shall not be violated:

pH DWS FBC, PBC, A&W 1 AgI AgL

Maximum 9.0 9.0 9.0 9.0

Minimum 5.0 6.5 4.5 6.5

Maximum change

due to discharge NNS 0.5 NNS NNS

C. The following maximum allowable increase in ambient water temperature, expressed in degrees Celsius, shall not be exceeded:

Temperature A&Ww, A&Wedw A&Wc

Maximum increase

due to a thermal discharge 2,3 3.0 1.0

D. The following water quality standard for suspended sediment concentration, expressed as a geometric mean (four-sample minimum) shall not be exceeded. The standard applies to a surface water that is at or near base flow and does not apply to a surface water during or soon after a precipitation event:

A&Wc, A&Ww

80 mg / L

E. The following are the water quality standards for dissolved oxygen, expressed in milligrams per liter (mg/L). The dissolved oxygen concentration in a surface water shall not fall below the following minimum concentrations:

1. Dissolved oxygen A&Ww A&Wc

Single sample minimum 4 6.0 7.0

2. Dissolved oxygen in effluent-dependent waters

(single sample minimum): A&W edw

Three hours after sunrise to sunset 3.0

Sunset to three hours after sunrise 1.0

3. A surface water is in compliance with the water quality standard for dissolved oxygen if the percent saturation of dissolved oxygen is equal to or greater than 90%.

F. The following water quality standards for total phosphorus and total nitrogen, expressed in milligrams per liter (mg/L), shall not be exceeded:

 

 

 

Annual Mean

90th percentile

Single Sample Maximum

1. Verde River and its tributaries from headwaters to Bartlett Lake:

Total phosphorus

Total nitrogen

0.10

1.00

0.30

1.50

1.00

3.00

2. Black River, Tonto Creek, and their tributaries that are not located on tribal lands:

Total phosphorus

Total nitrogen

0.10

0.50

0.20

1.00

0.80

2.00

3. Salt River and its tributaries that are not located on tribal lands but not Pinal Creek above Theodore Roosevelt Lake:

Total phosphorus

Total nitrogen

0.12

0.60

0.30

1.20

1.00

2.00

4. Theodore Roosevelt, Apache, Canyon, and Saguaro Lakes:

Total phosphorus

Total nitrogen

0.03 5

0.30 5

NNS

NNS

0.60 6

1.00 6

5. Salt River below Stewart Mountain Dam to confluence with the Verde River:

Total phosphorus

Total nitrogen

0.05

0.60

NNS

NNS

0.20

3.00

6. Little Colorado River and its tributaries above River Reservoir in Greer, South Fork of Little Colorado River above South Fork Campground, Water Canyon Creek above Apache-Sitgreaves National Forest boundary:

Total phosphorus

Total nitrogen

0.08

0.60

0.10

0.75

0.75

1.10

7. Little Colorado River at the crossing of Apache County Road No. 124:

Total phosphorus

Total nitrogen

NNS

NNS

NNS

NNS

0.75

1.80

8. Little Colorado River above Lyman Lake to above the Amity Ditch diversion near crossing of Arizona Highway 273 (applies only when in-stream turbidity is less than 50 NTU):

Total phosphorus

Total nitrogen

0.20

0.70

0.30

1.20

0.75

1.50

9. Colorado River, at Northern International Boundary near Morelos Dam:

Total phosphorus

Total nitrogen

NNS

NNS

0.33

2.50

NNS

NNS

10. San Pedro River, from Curtis to Benson:

Total phosphorus

Total nitrate as N

NNS

NNS

NNS

NNS

NNS

10.00

11. The discharge of wastewater to Show Low Creek and tributaries upstream of and including Fools Hollow Lake shall not exceed 0.16 mg/L total phosphates as P.

 

 

 

 

12. The discharge of wastewater to the San Francisco River and tributaries upstream of Luna Lake Dam shall not exceed 1.0 mg/L total phosphates as P.

 

 

 

 

G. The following water quality standards for radiochemicals shall not be exceeded in surface waters with the domestic water source designated use:

1. The concentration of gross alpha particle activity, including radium-226, but excluding radon and uranium, shall not exceed 15 picocuries per liter of water.

2. The concentration of combined radium-226 and radium-228 shall not exceed five picocuries per liter of water.

3. The concentration of strontium-90 shall not exceed 8 eight picocuries per liter of water.

4. The concentration of tritium shall not exceed 20,000 picocuries per liter of water.

5. The average annual concentration of beta particle activity and photon emitters from manmade radionuclides shall not produce an annual dose equivalent to the total body or any internal organ greater than four millirems per year.

Footnotes:

1 Includes A&Wc, A&Ww, A&Wedw, and A&We.

2 Does not apply to Cholla Lake.

3 Does not apply to a wastewater treatment plant discharge to a dry watercourse that creates an effluent-dependent water or to a stormwater discharge.

4 The dissolved oxygen water quality standard for a lake shall apply below the surface but not at a depth greater than one meter.

5 Means the annual mean of representative composite samples taken from the surface and at two and five meter depths.

6 Means the maximum for any set of representative composite samples taken from the surface and at two and five meter depths.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-110. Salinity Standards for the Colorado River

A. The flow-weighted average annual salinity in the lower main stem of the Colorado River shall be maintained at or below the following concentrations:

Location Total Dissolved Solids

Below Hoover Dam 723 mg/L

Below Parker Dam 747 mg/L

At Imperial Dam 879 mg/L

B. To preserve the basin-wide approach to salinity control developed by the Colorado River Basin states and to ensure compliance with the numeric criteria for salinity in subsection (A), the Department adopts the plan of implementation contained in the "1999 Review, Water Quality Standards for Salinity, Colorado River System," Colorado River Basin Salinity Control Forum, 106 West 500 South, Suite 101, Bountiful, Utah 84010-6232 (June, 1999), which is incorporated by reference and on file with the Office of the Secretary of State and the Department. This incorporation by reference contains no future editions or amendments.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-111. Analytical Methods

A. A person conducting an analysis of a sample taken to determine compliance with a water quality standard shall use an approved analytical method prescribed in 9 A.A.C. 14, Article 6, or an alternative analytical method that is approved by the Director of the Arizona Department of Health Services under R9-16-610(B).

B. A test result from a sample taken to determine compliance with a water quality standard is valid only if the sample is analyzed by a laboratory that is licensed by the Arizona Department of Health Services for the analysis performed.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-112. Unique Waters

A. The Director shall classify a surface water as a unique water by rule. The Director shall consider nominations to classify a surface water as a unique water during the triennial review of water quality standards for surface waters.

B. The Director may adopt, by rule, site-specific water quality standards to maintain and protect existing water quality in a unique water.

C. Any person may nominate a surface water for classification as a unique water by filing a nomination with the Department. The nomination to classify a surface water as a unique water shall include:

1. A map and a description of the surface water;

2. A written statement in support of the nomination, including specific reference to the applicable criteria for unique water classification prescribed in subsection (D);

3. Supporting evidence demonstrating that the applicable unique water criteria prescribed in subsection (D) are met; and

4. Available water quality data relevant to establishing the baseline water quality of the proposed unique water.

D. The Director may classify a surface water as a unique water upon finding that the surface water is an outstanding state resource water based upon the following criteria:

1. The surface water is a perennial water;

2. The surface water is in a free-flowing condition. For purposes of this subsection, "in a free-flowing condition" means that a surface water does not have an impoundment, diversion, channelization, rip-rapping or other bank armor, or another hydrological modification within the reach nominated for unique water classification;

3. The surface water has good water quality. For purposes of this subsection, "good water quality" means that the surface water has water quality that meets or exceeds applicable surface water quality standards. A surface water that is listed as impaired under § 303(d) of the Clean Water Act (33 U.S.C. § 1313) is ineligible for unique waters classification; and

4. The surface water meets one or both of the following conditions:

a. The surface water is of exceptional recreational or ecological significance because of its unique attributes, including but not limited to, attributes related to the geology, flora, fauna, water quality, aesthetic values, or the wilderness characteristics of the surface water.

b. Threatened or endangered species are known to be associated with the surface water and the existing water quality is essential to the maintenance and propagation of a threatened or endangered species or the surface water provides critical habitat for a threatened or endangered species. Endangered or threatened species are identified in Endangered and Threatened Wildlife and Plants, 50 CFR § 17.11 and § 17.12 (revised as of October 1, 2000) which is incorporated by reference and on file with the Department and the Office of the Secretary of State. This incorporation by reference contains no future editions or amendments.

E. The following surface waters are classified as unique waters:

1. The West Fork of the Little Colorado River, above Government Springs;

2. Oak Creek, including the West Fork of Oak Creek;

3. Peoples Canyon Creek, tributary to the Santa Maria River;

4. Burro Creek, above its confluence with Boulder Creek;

5. Francis Creek, in Mohave and Yavapai counties;

6. Bonita Creek, tributary to the upper Gila River;

7. Cienega Creek, from confluence with Gardner Canyon and Spring Water Canyon at R18E T17S to USGS gaging station at 32°02'09" / 110°40'34", in Pima County;

8. Aravaipa Creek, from its confluence with Stowe Gulch to the downstream boundary of Aravaipa Canyon Wilderness Area;

9. Cave Creek and the South Fork of Cave Creek (Chircahua Mountains), from the headwaters to the Coronado National Forest boundary;

10. Buehman Canyon Creek, from its headwaters (Lat. 32°24'55.5" N, Long. 110°39'43.5"W) to approximately 9.8 miles downstream (Lat. 32°24'31.5" N, Long. 10°32'08" W);

11. Lee Valley Creek, from its headwaters to Lee Valley Reservoir;

12. Bear Wallow Creek, from its headwaters to the boundary of the San Carlos Indian Reservation;

13. North Fork of Bear Wallow Creek, from its headwaters to Bear Wallow Creek;

14. South Fork of Bear Wallow Creek, from its headwaters to Bear Wallow Creek;

15. Snake Creek, from its headwaters to its confluence with Black River;

17. Hay Creek, from its headwaters to its confluence with the West Fork of the Black River;

18. Stinky Creek, from the Fort Apache Indian Reservation boundary to its confluence with the West Fork of the Black River; and

19. KP Creek, from its headwaters to its confluence with the Blue River.

F. The Department shall hold at least one public meeting in the local area of a nominated unique water to solicit public comment on the nomination.

G. The Director may consider the following factors when making a decision whether to classify a nominated surface water as a unique water:

1. Whether there is the ability to manage the unique water and its watershed to maintain and protect existing water quality;

2. The social and economic impact of Tier 3 antidegradation protection;

3. The public comments in support or opposition to a unique waters classification;

4. The support or opposition of federal and state land management and natural resources agencies to a nomination;

5. Agency resource constraints;

6. The timing of the unique water nomination relative to the triennial review of surface water quality standards;

7. The consistency of a unique water classification with applicable water quality management plans (for example, § 208 water quality management plans); and

8. Whether the nominated surface water is located within a national or state park, national monument, national recreation area, wilderness area, riparian conservation area, area of critical environmental concern, or it has another special use designation (for example, Wild and Scenic River designation).

H. The following water quality standards apply to the listed unique waters. Water quality standards prescribed in this subsection supplement the water quality standards prescribed by this Article.

1.

The West Fork of the Little Colorado River, above Government Springs:

 

Parameter

Standard

 

pH (standard units)

No change due to discharge

 

Temperature

No increase due to discharge

 

Dissolved oxygen

No decrease due to discharge

 

Total dissolved solids

No increase due to discharge

 

Chromium (as Cr)(D)

10 µg/L

2.

Oak Creek, including the West Fork of Oak Creek:

 

Parameter

Standard

 

pH (standard units)

No change due to discharge

 

Nitrogen (T)

1.00 mg / L (annual mean)

 

 

1.50 mg / L (90th percentile)

 

 

2.50 mg / L (single sample max.)

 

Phosphorus (T)

0.10 mg/L (annual mean)

 

 

0.25 mg/L (90th percentile)

 

 

0.30 mg/ L (single sample max.)

 

Chromium (as Cr) (D)

5 µg/L

 

Turbidity change due to discharge

3 NTUs

3.

Peoples Canyon Creek, tributary to the Santa Maria River:

 

Parameter

Standard

 

Temperature

No increase due to discharge

 

Dissolved oxygen

No decrease due to discharge

 

Turbidity change due to discharge

5 NTUs

 

Arsenic (T)

20 µg/L

 

Manganese (T)

500 µg/L

4.

Burro Creek, above its confluence with Boulder Creek:

 

Parameter

Standard

 

Manganese (T)

500 µg/L

5.

Francis Creek, in Mohave and Yavapai counties:

 

Parameter

Standard

 

Manganese (T)

500 µg/L

6.

Cienega Creek, from its confluence with Gardner Canyon and Spring Water Canyon at R18E T17S to Del Lago Dam, in Pima County:

 

Parameter

Standard

 

pH

No change due to discharge

 

Temperature

No increase due to discharge

 

Dissolved oxygen

No decrease due to discharge

 

Total dissolved solids

No increase due to discharge

 

Turbidity

10 NTUs

7.

Bonita Creek, tributary to the Upper Gila River:

 

Parameter

Standard

 

pH

No change due to discharge

 

Temperature

No increase due to discharge

 

Dissolved oxygen

No decrease due to discharge

 

Total dissolved solids

No increase due to discharge

 

Turbidity

15 NTUs

Abbreviations:

"(D)" means dissolved fraction

"(T)" means total recoverable

"NTUs" means nephelometric turbidity units

"mg / L" means milligrams per liter

"µg / L" means micrograms per liter

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Added "water quality standards" to R18-11-112, previously omitted in error (Supp. 96-3). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-113. Effluent-dependent Waters

A. The Director shall classify a surface water as an effluent-dependent water by rule.

B. The Director may adopt, by rule, site-specific water quality standards for an effluent-dependent water.

C. Any person may submit a petition for rule adoption requesting that the Director classify a surface water as an effluent-dependent water. The petition for rule adoption shall include:

1. A map and a description of the surface water,

2. Information that demonstrates that the surface water consists of discharges of treated wastewater, and

3. Information that demonstrates that the receiving water is an ephemeral water in the absence of the discharge of treated wastewater.

D. The following surface waters are classified as effluent-dependent waters:

1. In the Colorado River Main Stem Basin:

a. Bright Angel Wash from the South Rim Grand Canyon WWTP outfall to its confluence with Coconino Wash,

b. Cataract Creek from the Williams WWTP outfall to one kilometer downstream from the outfall,

c. Holy Moses Wash from the Kingman WWTP outfall to three kilometers downstream from the outfall, and

d. Transept Canyon from the North Rim Grand Canyon WWTP outfall to one kilometer downstream from the outfall.

2. In the Little Colorado River Basin:

a. Dry Lake,

b. Lake Humphreys,

c. Lower Walnut Canyon Lake,

d. Ned Lake,

e. Pintail Lake,

f. Telephone Lake,

g. Rio de Flag from the City of Flagstaff WWTP outfall to its confluence with San Francisco Wash, and

h. Whale Lake.

3. In the Middle Gila River Basin:

a. Unnamed wash from the Town of Prescott Valley WWTP outfall to its confluence with the Agua Fria River, and the Agua Fria River below its confluence with the unnamed wash receiving treated wastewater from the Prescott Valley WWTP to State Route 169;

b. Agua Fria river from the El Mirage WWTP outfall to two kilometers downstream from the outfall;

c. Gila River from the Florence WWTP outfall to Felix Road,

d. Gila River from its confluence with the Salt River to Gillespie Dam;

e. Queen Creek from the Town of Superior WWTP outfall to its confluence with Potts Canyon;

f. Unnamed wash from the Gila Bend WWTP outfall to its confluence with the Gila River;

g. Unnamed wash from the Luke AFB WWTP outfall to its confluence with the Agua Fria River; and

h. Unnamed wash from the Queen Valley WWTP outfall to its confluence with Queen Creek.

4. In the Rios de Mexico Basin:

a. Mule Gulch, from the Bisbee WWTP outfall to the Highway 80 bridge, and

b. Unnamed wash from the Bisbee-Douglas International Airport WWTP outfall to Whitewater Draw.

5. In the Salt River Basin:

a. Unnamed wash from the Globe WWTP outfall to its confluence with Pinal Creek and Pinal Creek from its confluence with the unnamed wash to Radium, and

b. Salt River from the 23rd Avenue WWTP outfall to its confluence with the Gila River.

6. In the San Pedro River Basin:

a. Unnamed wash from the Mt. Lemmon WWTP outfall to 0.25 kilometers downstream, and

b. Walnut Gulch from the Tombstone WWTP outfall to its confluence with Tombstone Gulch.

7. In the Santa Cruz Basin:

a. Santa Cruz River from the Nogales International WWTP outfall to Tubac Bridge,

b. Santa Cruz River from the Roger Road WWTP outfall to Baumgartner Road crossing,

c. Unnamed wash from the Oracle WWTP outfall to five kilometers downstream, and

d. Sonoita Creek from the Town of Patagonia WWTP outfall to 750 feet downstream.

8. In the Upper Gila River Basin:

a. Bennett Wash from the Arizona Department of Corrections-Safford WWTP outfall to the Gila River. and

b. Unnamed wash from the Arizona Department of Corrections-Globe WWTP outfall to the boundary of the San Carlos Indian Reservation.

9. In the Verde River Basin:

a. American Gulch from the Northern Gila County Sanitary District WWTP outfall to the East Verde River,

b. Bitter Creek from the Jerome WWTP outfall to 2.5 kilometers downstream from the outfall, and

c. Jacks Canyon Wash from the Big Park WWTP outfall to its confluence with Dry Beaver Creek.

10. In the Willcox Playa Basin: Lake Cochise

E. The NPDES permit issuing authority shall use the water quality standards that apply to an effluent-dependent water to derive discharge limitations for a point source discharge from a wastewater treatment plant to an ephemeral water that changes that ephemeral water into an effluent-dependent water.

F. The site-specific standard of 36 µg / L for dissolved copper for the aquatic and wildlife (effluent-dependent water) designated use applies to the Rio de Flag from the City of Flagstaff WWTP outfall to its confluence with the San Francisco Wash.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective December 18, 1992 (Supp. 92-4). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-114. Mixing Zones

A. The Director may establish a mixing zone for a point source discharge to a surface water as a condition of a NPDES permit. Mixing zones are prohibited in ephemeral waters or where there is no water for dilution.

B. The owner or operator of a point source seeking the establishment of a mixing zone shall submit a mixing zone application to the Department on a standard form that is available from the Department. The application shall include:

1. Identification of the pollutant for which the mixing zone is requested;

2. A proposed outfall design;

3. A definition of the boundary of the proposed mixing zone. For purposes of this subsection, the boundary of a mixing zone means the location where the concentration of treated wastewater across a transect of the surface water differs by less than 5%; and

4. A complete and detailed description of the existing physical, biological, and chemical conditions of the receiving water and the predicted impact of the proposed mixing zone on those conditions.

C. The Department shall review the application for a mixing zone to determine whether the application is complete. If the application is incomplete, the Department shall identify in writing the additional information that must be submitted to the Department to complete the mixing zone application.

D. The Director shall consider the following factors when deciding whether to grant or deny a request for a mixing zone:

1. The assimilative capacity of the receiving water;

2. The likelihood of adverse human health effects;

3. The location of drinking water plant intakes and public swimming areas;

4. The predicted exposure of biota and the likelihood that resident biota will be adversely affected;

5. Bioaccumulation and bioconcentration;

6. Whether there will be acute toxicity in the mixing zone, and, if so, the size of the area of acute toxicity;

7. The known or predicted safe exposure levels for the pollutant of concern;

8. The size of the mixing zone;

9. The location of the mixing zone relative to biologically sensitive areas in the surface water;

10. The concentration gradient of the pollutant within the mixing zone;

11. Sediment deposition;

12. The potential for attracting aquatic life to the mixing zone; and

13. The cumulative impacts of other mixing zones and other discharges to the surface water.

E. The Director shall deny the request to establish a mixing zone if water quality standards outside the boundaries of the proposed mixing zone will be violated. The denial of a request for a mixing zone shall be in writing and shall state the reason for the denial. If the Director determines that a mixing zone should be established, the Director shall establish the mixing zone as a condition of a NPDES permit. The Director may include mixing zone conditions in the NPDES permit that the Director deems necessary to protect human health and the designated uses of the surface water.

F. Any person who is adversely affected by the Director's decision to grant or deny a request for a mixing zone may appeal the decision to an administrative law judge under A.R.S. § 49-321 and A.R.S. § 41-1092 et seq.

G. The Department shall reevaluate a mixing zone upon issuance, reissuance, or modification of the National Pollutant Discharge Elimination System permit for the point source or a modification of the outfall structure.

H. The length of a mixing zone shall not exceed 500 meters in a stream. The total horizontal area allocated to all mixing zones on a lake shall not exceed 10% of the surface area of the lake. Adjacent mixing zones in a lake shall be no closer than the greatest horizontal dimension of any individual mixing zone.

I. A mixing zone shall provide for a zone of passage of not less than 50% of the cross-sectional area of a river or stream.

J. The discharge outfall shall be designed to maximize initial dilution of the treated wastewater in a surface water.

K. A mixing zone is prohibited for the following persistent, bioaccumulative pollutants:

1. Chlordane,

2. DDT and its metabolites (DDD and DDE),

3. Dieldrin,

4. Dioxin,

5. Endrin,

6. Endrin aldehyde,

7. Heptachlor,

8. Heptachlor epoxide,

9. Lindane,

10. Mercury,

11. PCBs, and

12. Toxaphene.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-115. Repealed

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Section repealed by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-116. Resource management agencies

Nothing in this Article shall be construed to prohibit fisheries management activities by the Arizona Game and Fish Department or the U.S. Fish and Wildlife Service. This provision does not exempt fish hatcheries from National Pollutant Discharge Elimination System permit requirements.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1).

R18-11-117. Canals and Municipal Park Lakes

A. Nothing in this Article shall be construed to prevent the routine physical or mechanical maintenance of canals, drains, and the municipal park lakes identified in Appendix B. Physical or mechanical maintenance includes dewatering, lining, dredging, and the physical, biological or chemical control of weeds and algae. Increases in turbidity that result from physical or mechanical maintenance activities are permitted in canals, drains, and the municipal park lakes identified in Appendix B.

B. The discharge of lubricating oil that is associated with the start-up of well pumps which discharge to canals is not a violation of R18-11-108(B).

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2).

R18-11-118. Dams and Flood Control Structures

A. Increases in turbidity that result from the routine physical or mechanical maintenance of a dam or flood control structure are not violations of this Article.

B. Nothing in this Article shall be construed to require the release of water from a dam or a flood control structure.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-119. Natural background

Where the concentration of a pollutant exceeds a water quality standard and the exceedance is not caused by human activity but is due solely to naturally-occurring conditions, the exceedance shall not be considered a violation of the water quality standard.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1).

R18-11-120. Enforcement

A. Any person who causes a violation of a water quality standard or any provision of this Article is subject to the enforcement provisions in A.R.S. Title 49, Chapter 2, Article 4.

B. The Department may establish a numeric water quality standard at a concentration that is below the practical quantitation limit. In such cases, the water quality standard is enforceable at the practical quantitation limit.

C. The Department shall determine compliance with acute aquatic and wildlife criteria from the analytical result of a grab sample. Compliance with chronic aquatic and wildlife criteria shall be determined from the geometric mean of the analytical results of the last four samples taken at least 24 hours apart.

D. A person is not subject to penalties for violation of a water quality standard provided that the person is in compliance with the provisions of a compliance schedule issued under R18-11-121.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-121. Schedules of Compliance

A. A schedule to bring an existing point source into compliance with a new or revised water quality standard may be established in a National Pollutant Discharge Elimination System permit for an existing point source. A compliance schedule for an existing point source, other than a storm water discharge, shall require compliance with a discharge limitation based upon a new or revised water quality standard no later than three years after the effective date of the National Pollutant Discharge Elimination System permit. For a schedule of compliance to be granted, the owner or operator of the existing point source shall demonstrate that all requirements under § 301(b) and § 306 of the Clean Water Act [33 U.S.C. § 1311(b) and § 1316] have been achieved and that the point source cannot comply with a discharge limitation based upon the new or revised water quality standard through the application of existing water pollution control technology, operational changes, or source reduction.

B. A schedule of compliance may be established in a National Pollutant Discharge Elimination System permit for a new point source. The first National Pollutant Discharge Elimination System permit issued to a new point source may contain a schedule of compliance only when necessary to allow a reasonable opportunity to attain compliance with a new or revised water quality standard that becomes effective after commencement of construction but less than three years before commencement of the discharge. For purposes of this subsection, commencement of construction means that the owner or operator of the point source has obtained the federal, state, and local approvals or permits necessary to begin physical construction of the point source and either:

1. Onsite physical construction has begun; or

2. The owner or operator has entered into a contract for physical construction of the point source and the contract cannot be cancelled or modified without substantial loss. For purposes of this subsection, "substantial loss" means in excess of 10% of the total cost incurred for physical construction.

C. A schedule of compliance may be established in a National Pollutant Discharge Elimination System permit for a recommencing point source discharge. The first National Pollutant Discharge Elimination System permit issued to a recommencing point source discharge may contain a schedule of compliance only when necessary to allow a reasonable opportunity to attain compliance with a new or revised water quality standard that becomes effective less than three years before recommencement of discharge.

D. A schedule to bring a point source discharge of storm water into compliance with a water quality standard may be established in a National Pollutant Discharge Elimination System permit. A compliance schedule for a storm water discharge shall require implementation of all reasonable and cost-effective best management practices to control the discharge of pollutants in storm water.

Historical Note

Adopted effective February 18, 1992 (Supp. 92-1). Amended effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-122. Variances

A. The Director may grant a variance from a water quality standard for a point source discharge if the discharger demonstrates that treatment more advanced than that required to comply with technology-based effluent limitations is necessary to comply with the water quality standard and:

1. It is not technically feasible to achieve compliance within the next five years,

2. The cost of the treatment would result in substantial and widespread economic and social impact, or

3. Human-caused conditions or sources of pollution prevent attainment of the water quality standard and cannot be remedied within the next five years.

B. A variance may be granted only on a pollutant-specific basis. A point source discharge is required to comply with all other applicable water quality standards for which a variance is not granted.

C. A variance applies only to a specific point source discharge. The granting of a variance does not modify a water quality standard. Other point source dischargers to the surface water shall comply with applicable water quality standards, including any water quality standard for which a variance has been granted for a specific point source discharge.

D. A variance is for a fixed term not to exceed five years. Upon expiration of a variance, a point source discharger shall either comply with the water quality standard or apply for renewal of the variance. To renew a variance, the applicant shall demonstrate reasonable progress towards compliance with the water quality standard during the term of the variance.

E. The Department shall reevaluate a variance upon the issuance, reissuance, or modification of the National Pollutant Discharge Elimination System permit for the point source discharge.

F. A person who seeks a variance from a water quality standard shall submit a written request for a variance to the Department. A request for a variance shall include the following information:

1. Identification of the specific pollutant and water quality standard for which a variance is sought;

2. Identification of the receiving surface water;

3. For an existing point source discharge, a detailed description of the existing discharge control technologies that are used to achieve compliance with applicable water quality standards. For a new point source discharge, a detailed description of the proposed discharge control technologies that will be used to achieve compliance with applicable water quality standards;

4. Documentation that the existing or proposed discharge control technologies will comply with applicable technology-based effluent limitations and that more advanced treatment technology is necessary to achieve compliance with the water quality standard for which a variance is sought;

5. A detailed discussion of the reasons why compliance with the water quality standard cannot be achieved;

6. A detailed discussion of the discharge control technologies that are available for achieving compliance with the water quality standard for which a variance is sought;

7. Documentation of one of the following:

a. That it is not technically feasible to install and operate any of the available discharge control technologies to achieve compliance with the water quality standard for which a variance is sought,

b. That installation and operation of each of the available discharge technologies to achieve compliance with the water quality standard would result in substantial and widespread economic and social impact, or

c. That human-caused conditions or sources of pollution prevent the attainment of the water quality standard for which the variance is sought and it is not possible to remedy the conditions or sources of pollution within the next five years,

8. Documentation that the point source discharger has reduced, to the maximum extent practicable, the discharge of the pollutant for which a variance is sought through implementation of a local pretreatment, source reduction, or waste minimization program, and

9. A detailed description of proposed interim discharge limitations that represent the highest level of treatment achievable by the point source discharger during the term of the variance. Interim discharge limitations shall not be less stringent than technology-based effluent limitations.

G. In making a decision on whether to grant or deny the request for a variance, the Director shall consider the following factors:

1. Bioaccumulation and bioconcentration,

2. The predicted exposure of biota and the likelihood that resident biota will be adversely affected,

3. The known or predicted safe exposure levels for the pollutant of concern, and

4. The likelihood of adverse human health effects.

H. The Department shall issue a public notice and shall provide an opportunity for a public hearing on whether the request for a variance should be granted or denied under procedures prescribed in R18-1-401 and R18-1-402.

I. Any person who is adversely affected by a decision of the Director to grant or deny a variance may appeal the decision to an administrative law judge under A.R.S. § 49-321 and A.R.S. § 41-1092 et seq.

J. The Department shall not grant a variance for a point source discharge to a unique water listed in R18-11-112.

K. A variance is subject to review and approval by the Regional Administrator of the U.S. Environmental Protection Agency.

Historical Note

Adopted effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

R18-11-123. Prohibition Against Discharge

A. The discharge of treated wastewater to Sabino Creek is prohibited.

B. The discharge of human body wastes and the wastes from toilets and other receptacles intended to receive or retain those wastes on a vessel to Lake Powell is prohibited.

Historical Note

Adopted effective April 24, 1996 (Supp. 96-2). Amended by final rulemaking at 8 A.A.R. 1264, effective March 8, 2002 (Supp. 02-1).

 

Appendix A: Numeric Water Quality Criteria

Table 1. Human Health and Agricultural Designated Uses

PARAMETER

CAS*

NUMBER

DWS

(µg/L)

FC

(µg/L)

FBC

(µg/L)

PBC

(µg/L)

AgI

(µg/L)

AgL

(µg/L)

Acenaphthene

83-32-9

420

2670

84,000

84,000

NNS

NNS

Acenaphthylene

208-96-8

NNS

NNS

NNS

NNS

NNS

NNS

Acrolein

107-02-8

3.5

25

700

700

NNS

NNS

Acrylonitrile

107-13-1

0.07

0.7

3

56,000

NNS

NNS

Alachlor

15972-60-8

2

NNS

14,000

14,000

NNS

NNS

Aldrin

309-00-2

0.002

0.0001

0.08

42

p

p

Ammonia

7664-41-7

NNS

NNS

NNS

NNS

NNS

NNS

Anthracene

120-12-7

2100

1000

420,000

420,000

NNS

NNS

Antimony (as Sb)

7440-36-0

6 T

4,300 T

560 T

560 T

NNS

NNS

Arsenic (as As)

7440-38-2

50 T

1450 T

50 T

420 T

2000 T

200 T

Asbestos

1332-21-4

a

NNS

NNS

NNS

NNS

NNS

Atrazine

1912-24-9

3

NNS

49,000

49,000

NNS

NNS

Barium (as Ba)

7440-39-3

2000 T

NNS

98,000 T

98,000 T

NNS

NNS

Benzene

71-43-2

5

140

93

93

NNS

NNS

Benzidine

92-87-5

0.0002

0.001

0.01

4,200

0.01

0.01

Benz (a) anthracene

56-55-3

0.048

0.49

1.9

1.9

NNS

NNS

Benzo (a) pyrene

50-32-8

0.2

0.05

0.2

0.2

NNS

NNS

Benzo (ghi) perylene

191-24-2

NNS

NNS

NNS

NNS

NNS

NNS

Benzo (k) fluoranthene

207-08-9

0.048

0.49

1.9

1.9

NNS

NNS

3,4-Benzofluoranthene

205-99-2

0.048

0.49

1.9

1.9

NNS

NNS

Beryllium (as Be)

7440-41-7

4 T

1,130 T

2,800 T

2,800 T

NNS

NNS

Bis (2-chloroethoxy) methane

111-91-1

NNS

NNS

NNS

NNS

NNS

NNS

Bis (2-chloroethyl) ether

111-44-4

0.03

1.4

1.3

1.3

NNS

NNS

Bis (2-chloroisopropyl) ether

108-60-1

280

174,400

56,000

56,000

NNS

NNS

Boron (as B)

7440-42-8

630 T

NNS

126,000 T

126,000 T

1000 T

NNS

Bromodichloromethane

75-27-4

TTHM

46

TTHM

28,000

NNS

NNS

p-Bromodiphenyl ether

101-55-3

NNS

NNS

NNS

NNS

NNS

NNS

Bromoform

75-25-2

TTHM

360

180

28,000

NNS

NNS

Bromomethane

74-83-9

9.8

4020

2000

2000

NNS

NNS

Butyl benzyl phthalate

85-68-7

1400

5200

280,000

280,000

NNS

NNS

Cadmium (as Cd)

7440-43-9

5 T

84 T

700 T

700 T

50 T

50 T

Carbofuran

1563-66-2

40

NNS

7,000

7,000

NNS

NNS

Carbon tetrachloride

56-23-5

5

4

11

980

NNS

NNS

Chlordane

57-74-9

2

0.002

4

700

NNS

NNS

Chlorine (total residual)

7782-50-5

700

NNS

140,000

140,000

NNS

NNS

Chlorobenzene

108-90-7

100

20,900

28,000

28,000

NNS

NNS

p-Chloro-m-cresol

59-50-7

NNS

NNS

NNS

NNS

NNS

NNS

2-Chloroethyl vinyl ether

110-75-8

NNS

NNS

NNS

NNS

NNS

NNS

Chloroform

67-66-3

TTHM

470

230

14,000

NNS

NNS

Chloromethane

74-87-3

NNS

NNS

NNS

NNS

NNS

NNS

Chloronapthalene beta

91-58-7

560

4,300

112,000

112,000

NNS

NNS

2-Chlorophenol

95-57-8

35

400

7,000

7,000

NNS

NNS

4-Chlorophenyl phenyl ether

7005-72-3

NNS

NNS

NNS

NNS

NNS

NNS

Chromium (as Cr III)

16065-83-1

10,500 T

1,010,000 T

2,100,000 T

2,100,000 T

NNS

NNS

Chromium (as Cr VI)

18540-29-9

21 T

2,000T

4,200 T

4,200 T

NNS

NNS

Chromium (Total as Cr)

7440-47-3

100 T

NNS

100 T

100 T

1000 T

1000 T

Chrysene

218-01-9

0.479

4.92

19.2

19

NNS

NNS

Copper (as Cu)

7440-50-8

1,300 T

NNS

1,300 T

1,300 T

5000 T

500 T

Cyanide

57-12-5

200 T

215,000 T

28,000 T

28,000 T

NNS

200 T

Dalapon

75-99-0

200

161,500

42,000

42,000

NNS

NNS

Dibenz (ah) anthracene

53-70-3

0.048

0.20

1.9

1.9

NNS

NNS

Dibromochloromethane

124-48-1

TTHM

34

TTHM

28,000

NNS

NNS

1,2-Dibromo-3-chloropropane (DBCP)

96-12-8

0.2

NNS

2,800

2,800

NNS

NNS

1,2-Dibromoethane (EDB)

106-93-4

0.05

NNS

0.05

0.05

NNS

NNS

Dibutyl phthalate

84-74-2

700

12,100

140,000

140,000

NNS

NNS

1,2-Dichlorobenzene

95-50-1

600

2800

126,000

126,000

NNS

NNS

1,3-Dichlorobenzene

541-73-1

NNS

NNS

NNS

NNS

NNS

NNS

1,4-Dichlorobenzene

106-46-7

75

77,500

560,000

560,000

NNS

NNS

3,3'-Dichlorobenzidine

91-94-1

0.08

0.08

3.1

3.1

NNS

NNS

p,p'-Dichlorodiphenyldichloroethane (DDD)

72-54-8

0.15

0.001

5.8

5.8

0.001

0.001

p,p'-Dichlorodiphenyldichloroethylene (DDE)

72-55-9

0.1

0.001

4.1

4.1

0.001

0.001

p,p'-Dichlorodiphenyltrichloroethane (DDT)

50-29-3

0.1

0.0006

4.1

700

0.001

0.001

1,1-Dichloroethane

75-34-3

NNS

NNS

NNS

NNS

NNS

NNS

1,2-Dichloroethane

107-06-2

5

100

15

280,000

NNS

NNS

1,1-Dichloroethylene

75-35-4

7

320

230

12,600

NNS

NNS

1,2-cis-Dichloroethylene

156-59-2

70

NNS

70

70

NNS

NNS

1,2-trans-Dichloroethylene

156-60-5

100

136,000

28,000

28,000

NNS

NNS

Dichloromethane

75-09-2

5

1600

190

84,000

NNS

NNS

2,4-Dichlorophenol

120-83-2

21

800

4,200

4,200

NNS

NNS

2,4-Dichlorophenoxyacetic acid (2,4-D)

94-75-7

70

NNS

14,000

14,000

NNS

NNS

1,2-Dichloropropane

78-87-5

5

236,000

126,000

126,000

NNS

NNS

1,3-Dichloropropene

542-75-6

2

1,700

420

420

NNS

NNS

Dieldrin

60-57-1

0.002

0.0001

0.09

70

p

p

Diethyl phthalate

84-66-2

5600

118,000

1,120,000

1,120,000

NNS

NNS

Di (2-ethylhexyl) adipate

103-23-1

400

NNS

1,200

840,000

NNS

NNS

Di (2-ethylhexyl) phthalate

117-81-7

6

7.4

100

28,000

NNS

NNS

2,4-Dimethylphenol

105-67-9

140

2300

28,000

28,000

NNS

NNS

Dimethyl phthalate

131-11-3

NNS

NNS

NNS

NNS

NNS

NNS

4,6-Dinitro-o-cresol

534-52-1

28

7,800

5,600

5,600

NNS

NNS

2,4-Dinitrophenol

51-28-5

14

14,400

2,800

2,800

NNS

NNS

2,4-Dinitrotoluene

121-14-2

14

5,700

2,800

2,800

NNS

NNS

2,6-Dinitrotoluene

606-20-2

0.05

NNS

2

5,600

NNS

NNS

Di-n-octyl phthalate

117-84-0

2800

NNS

560,000

560,000

NNS

NNS

Dinoseb

88-85-7

7

NNS

1,400

1,400

NNS

NNS

1,2-Diphenylhydrazine

122-66-7

0.04

0.5

1.8

1.8

NNS

NNS

Diquat

85-00-7

20

NNS

3,080

3,080

NNS

NNS

Endosulfan sulfate

1031-07-8

NNS

NNS

NNS

NNS

NNS

NNS

Endosulfan (Total)

115-29-7

42

240

8,400

8,400

NNS

NNS

Endothall

145-73-3

100

NNS

28,000

28,000

NNS

NNS

Endrin

72-20-8

2

0.8

420

420

0.004

0.004

Endrin aldehyde

7421-93-3

NNS

NNS

NNS

NNS

NNS

NNS

Ethylbenzene

100-41-4

700

28,700

140,000

140,000

NNS

NNS

Ethyl chloride

75-00-3

NNS

NNS

NNS

NNS

NNS

NNS

Fluoranthene

206-44-0

280

380

56,000

56,000

NNS

NNS

Fluorene

86-73-7

280

14,400

56,000

56,000

NNS

NNS

Fluoride

7782-41-4

4000

NNS

84,000

84,000

NNS

NNS

Glyphosate

1071-83-6

700

1,077,000

140,000

140,000

NNS

NNS

Heptachlor

76-44-8

0.4

0.0002

0.4

700

NNS

NNS

Heptachlor epoxide

1024-57-3

0.2

0.0001

0.2

18

NNS

NNS

Hexachlorobenzene

118-74-1

1

0.001

1

1,120

NNS

NNS

Hexachlorobutadiene

87-68-3

0.45

50

18

280

NNS

NNS

Hexachlorocyclohexane alpha

319-84-6

0.006

0.01

0.22

11,200

NNS

NNS

Hexachlorocyclohexane beta

319-85-7

0.02

0.02

0.78

840

NNS

NNS

Hexachlorocyclohexane delta

319-86-8

NNS

NNS

NNS

NNS

NNS

NNS

Hexachlorocyclohexane gamma (lindane)

58-89-9

0.2

25

420

420

NNS

NNS

Hexachlorocyclopentadiene

77-47-4

50

580

9,800

9,800

NNS

NNS

Hexachloroethane

67-72-1

2.5

9

100

1,400

NNS

NNS

Indeno (1,2,3-cd) pyrene

193-39-5

0.048

0.49

1.9

1.9

NNS

NNS

Isophorone

78-59-1

37

2,600

1,500

280,000

NNS

NNS

Lead (as Pb)

7439-97-1

15 T

NNS

15 T

15 T

10000 T

100 T

Manganese (as Mn)

7439-96-5

980 T

NNS

196,000 T

196,000 T

10000

NNS

Mercury (as Hg)

7439-97-6

2 T

0.6 T

420 T

420 T

NNS

10 T

Methoxychlor

72-43-5

40

NNS

7,000

7,000

NNS

NNS

Naphthalene

91-20-3

140

20,500

28,000

28,000

NNS

NNS

Nickel (as Ni)

7440-02-0

140 T

4,600 T

28,000 T

28,000 T

NNS

NNS

Nitrate (as N)

14797-55-8

10000

NNS

2,240,000

2,240,000

NNS

NNS

Nitrite (as N)

14797-65-0

1000

NNS

140,000

140,000

NNS

NNS

Nitrate/Nitrite (as Total N)

 

10000

NNS

NNS

NNS

NNS

NNS

Nitrobenzene

98-95-3

3.5

1,900

700

700

NNS

NNS

o-Nitrophenol

88-75-5

NNS

NNS

NNS

NNS

NNS

NNS

p-Nitrophenol

100-02-7

NNS

NNS

NNS

NNS

NNS

NNS

N-nitrosodimethylamine

62-75-9

0.001

8

0.03

0.03

NNS

NNS

N-nitrosodiphenylamine

86-30-6

7.1

16

290

290

NNS

NNS

N-nitrosodi-n-propylamine

621-64-7

0.005

1.4

0.2

133,000

NNS

NNS

Oxamyl

23135-22-0

200

NNS

35,000

35,000

NNS

NNS

Pentachlorophenol

87-86-5

1

1000

12

42,000

NNS

NNS

Phenanthrene

85-01-8

NNS

NNS

NNS

NNS

NNS

NNS

Phenol

108-95-2

4200

1,000

840,000

840,000

NNS

NNS

Picloram

1918-02-1

500

24,300

98,000

98,000

NNS

NNS

Polychlorinatedbiphenyls (PCBs)

1336-36-3

0.5

0.007

28

28

0.001

0.001

Pyrene

129-00-0

210

10,800

42,000

42,000

NNS

NNS

Selenium (as Se)

7782-49-2

50 T

9000 T

7,000 T

7,000 T

20 T

50 T

Silver (as Ag)

7440-22-4

35 T

107,700 T

7,000 T

7,000 T

NNS

NNS

Simazine

112-34-9

4

NNS

7,000

7,000

NNS

NNS

Styrene

100-42-5

100

NNS

280,000

280,000

NNS

NNS

Sulfides

 

NNS

NNS

NNS

NNS

NNS

NNS

2,3,7,8-Tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD)

1746-01-6

0.0000003

0.000000004

0.00009

1.4

NNS

NNS

1,1,2,2-Tetrachloroethane

79-34-5

0.17

11

7

56,000

NNS

NNS

Tetrachloroethylene

127-18-4

5

3,500

14,000

14,000

NNS

NNS

Thallium (as Tl)

7440-28-0

2 T

7.2 T

112 T

112 T

NNS

NNS

Toluene

108-88-3

1000

201,000

280,000

280,000

NNS

NNS

Toxaphene

8001-35-2

3

0.001

1.3

1400

0.005

0.005

1,2,4-Trichlorobenzene

120-82-1

70

950

14,000

14,000

NNS

NNS

1,1,1-Trichloroethane

71-55-6

200

NNS

200

200

1000

NNS

1,1,2-Trichloroethane

79-00-5

5

42

25

5,600

NNS

NNS

Trichloroethylene

79-01-6

5

203,200

280,000

280,000

NNS

NNS

2,4,6-Trichlorophenol

88-06-2

3.2

6.5

130

130

NNS

NNS

2-(2,4,5-Trichlorophenoxy) proprionic acid (2,4,5-TP)

93-72-1

50

NNS

11,200

11,200

NNS

NNS

Trihalomethanes, Total

 

100

NNS

NNS

NNS

NNS

NNS

Uranium (as Ur)

7440-61-1

35 D

NNS

NNS

NNS

NNS

NNS

Vinyl chloride

75-01-4

2

13

2

4,200

NNS

NNS

Xylenes (Total)

1330-20-7

10000

NNS

2,800,000

2,800,000

NNS

NNS

Zinc (as Zn)

7440-66-6

2100 T

69,000 T

420,000 T

420,000 T

10000 T

25000 T

 

*Chemical Abstract System (CAS) number is a unique identification number given to each chemical.

 

Appendix A: Numeric Water Quality Criteria

Table 2. Aquatic & Wildlife Designated Uses

PARAMETER

CAS

NUMBER

A&Wc

Acute

(µg/L)

A&Wc

Chronic

(µg/L)

A&Ww

Acute

(µg/L)

A&Ww

Chronic

(µg/L)

A&Wedw

Acute

(µg/L)

A&Wedw

Chronic

(µg/L)

A&We

Acute

(µg/L)

Acenaphthene

83-32-9

850

550

850

550

850

550

NNS

Acenaphthylene

208-96-8

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Acrolein

107-02-8

34

30

34

30

34

30

NNS

Acrylonitrile

107-13-1

3800

250

3800

250

3800

250

NNS

Alachlor

15972-60-8

2500

170

2500

170

2500

170

NNS

Aldrin

309-00-2

2.0

NNS

2.0

NNS

2.0

NNS

4.5

Ammonia

7664-41-7

b

b

b

b

NNS

NNS

NNS

Anthracene

120-12-7

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Antimony (as Sb)

7440-36-0

88 D

30 D

88 D

30 D

1000 D

600 D

NNS

Arsenic (as As)

7440-38-2

360 D

190 D

360 D

190 D

360 D

190 D

440 D

Asbestos

1332-21-4

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Atrazine

1912-24-9

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Barium (as Ba)

7440-39-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Benzene

71-43-2

2700

180

2700

180

8800

560

NNS

Benzidine

92-87-5

1300

89

1300

89

1300

89

10000

Benz (a) anthracene

56-55-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Benzo (a) pyrene

50-32-8

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Benzo (ghi) perylene

191-24-2

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Benzo (k) fluoranthene

207-08-9

NNS

NNS

NNS

NNS

NNS

NNS

NNS

3,4-Benzofluoranthene

205-99-2

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Beryllium (as Be)

7440-41-7

65 D

5.3 D

65 D

5.3 D

65 D

5.3 D

NNS

Bis (2-chloroethoxy) methane

111-91-1

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Bis (2-chlorethyl) ether

111-44-4

120000

6700

120000

6700

120000

6700

NNS

Bis (2-chloroisopropyl) ether

108-60-1

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Boron (as B)

7440-42-8

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Bromodichloromethane

75-27-4

NNS

NNS

NNS

NNS

NNS

NNS

NNS

p-Bromodiphenyl ether

101-55-3

180

14

180

14

180

14

NNS

Bromoform

75-25-2

15000

10000

15000

10000

15000

10000

NNS

Bromomethane

74-83-9

5500

360

5500

360

5500

360

NNS

Butyl benzyl phthalate

85-68-7

1700

130

1700

130

1700

130

NNS

Cadmium (as Cd)

7440-43-9

c D

c D

c D

c D

c D

c D

c D

Carbofuran

1563-66-2

650

50

650

50

650

50

NNS

Carbon tetrachloride

56-23-5

18000

1100

18000

1100

18000

1100

NNS

Chlordane

57-74-9

2.4

0.004

2.4

0.21

2.4

0.21

3.2

Chlorine (total residual)

7782-50-5

11

5.0

11

5.0

11

5.0

NNS

Chlorobenzene

108-90-7

3800

260

3800

260

3800

260

NNS

p-Chloro-m-cresol

59-50-7

15

4.7

15

4.7

15

4.7

48000

2-Chloroethyl vinyl ether

110-75-8

180000

9800

180000

9800

180000

9800

NNS

Chloroform

67-66-3

14000

900

14000

900

14000

900

NNS

Chloromethane

74-87-3

270000

15000

270000

15000

270000

15000

NNS

Chloronapthalene beta

91-58-7

NNS

NNS

NNS

NNS

NNS

NNS

NNS

2-Chlorophenol

95-57-8

2200

150

2200

150

2200

150

NNS

4-Chlorophenyl phenyl ether

7005-72-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Chromium (as Cr III)

16065-83-1

d D

d D

d D

d D

d D

d D

d D

Chromium (as Cr VI)

18540-29-9

16 D

11 D

16 D

11 D

16 D

11 D

34 D

Chromium (Total as Cr)

7440-47-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Chrysene

218-01-9

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Copper (as Cu)

7440-50-8

e D

e D

e D

e D

e D

e D

e D

Cyanide

57-12-5

22 T

5.2 T

41 T

9.7 T

41 T

9.7 T

84 T

Dibenz (ah) anthracene

53-70-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Dibromochloromethane

124-48-1

NNS

NNS

NNS

NNS

NNS

NNS

NNS

1,2-Dibromo-3-chloropropane (DBCP)

96-12-8

NNS

NNS

NNS

NNS

NNS

NNS

NNS

1,2-Dibromoethane (EDB)

106-93-4

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Dibutyl phthalate

84-74-2

470

35

470

35

470

35

1100

1,2-Dichlorobenzene

95-50-1

790

300

1200

470

1200

470

5900

1,3-Dichlorobenzene

541-73-1

2500

970

2500

970

2500

970

NNS

1,4-Dichlorobenzene

106-46-7

560

210

2000

780

2000

780

6500

3,3'-Dichlorobenzidine

91-94-1

NNS

NNS

NNS

NNS

NNS

NNS

NNS

p,p'-Dichlorodiphenyldichloroethane (DDD)

72-54-8

1.1

0.001

1.1

0.02

1.1

0.02

1.1

p,p'-Dichlorodiphenyldichloroethylene (DDE)

72-55-9

1.1

0.001

1.1

0.02

1.1

0.02

1.1

p,p'-Dichlorodiphenyltrichloroethane (DDT)

50-29-3

1.1

0.001

1.1

0.001

1.1

0.001

1.1

1,1-Dichloroethane

75-34-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

1,2-Dichloroethane

107-06-2

59000

41000

59000

41000

59000

41000

NNS

1,1-Dichloroethylene

75-35-4

15000

950

15000

950

15000

950

NNS

1,2-cis-Dichloroethylene

156-59-2

NNS

NNS

NNS

NNS

NNS

NNS

NNS

1,2-trans-Dichloroethylene

156-60-5

68000

3900

68000

3900

68000

3900

NNS

Dichloromethane

75-09-2

97000

5500

97000

5500

97000

5500

NNS

2,4-Dichlorophenol

120-83-2

1000

88

1000

88

1000

88

NNS

2,4-Dichlorophenoxyacetic acid (2,4-D)

94-75-7

NNS

NNS

NNS

NNS

NNS

NNS

NNS

1,2-Dichloropropane

78-87-5

26000

9200

26000

9200

26000

9200

NNS

1,3-Dichloropropene

542-75-6

3000

1100

3000

1100

3000

1100

NNS

Dieldrin

60-57-1

2.5

0.002

2.5

0.002

2.5

0.005

4

Diethyl phthalate

84-66-2

26000

1600

26000

1600

26000

1600

NNS

Di(2-ethylhexyl) phthalate

117-81-7

400

360

400

360

400

360

3100

2,4-Dimethylphenol

105-67-9

1000

310

1000

310

1100

310

150000

Dimethyl phthalate

131-11-3

17000

1000

17000

1000

17000

1000

NNS

4,6-Dinitro-o-cresol

534-52-1

310

24

310

24

310

24

NNS

2,4-Dinitrophenol

51-28-5

110

9.2

110

9.2

110

9.2

NNS

2,4-Dinitrotoluene

121-14-2

14000

860

14000

860

14000

860

NNS

2,6-Dinitrotoluene

606-20-2

NNS

NNS

NNS

NNS

NNS

NNS

NNS

-Di-n-octyl phthalate

117-84-0

NNS

NNS

NNS

NNS

NNS

NNS

NNS

1,2-Diphenylhydrazine

122-66-7

130

11

130

11

130

11

NNS

Endosulfan sulfate

1031-07-8

0.22

0.06

0.22

0.06

0.22

0.06

3.0

Endosulfan (Total)

115-29-7

0.22

0.06

0.22

0.06

0.22

0.06

3.0

Endrin

72-20-8

0.18

0.002

0.2

0.08

0.2

0.08

0.7

Endrin aldehyde

7421-93-3

0.18

0.002

0.2

0.08

0.2

0.08

0.7

Ethylbenzene

100-41-4

23000

1400

23000

1400

23000

1400

NNS

Ethyl chloride

75-00-3

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Fluoranthene

206-44-0

2000

1600

2000

1600

2000

1600

NNS

Fluorene

86-73-7

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Fluorine

7782-41-4

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Heptachlor

76-44-8

0.52

0.004

0.52

0.004

0.58

0.013

0.9

Heptachlor epoxide

1024-57-3

0.52

0.004

0.52

0.004

0.58

0.013

0.9

Hexachlorobenzene

118-74-1

6.0

3.7

NNS

NNS

NNS

NNS

NNS

Hexachlorobutadiene

87-68-3

45

8.2

45

8.2

45

8.2

NNS

Hexachlorocyclohexane alpha

319-84-6

1600

130

1600

130

1600

130

1600

Hexachlorocyclohexane beta

319-85-7

1600

130

1600

130

1600

130

1600

Hexachlorocyclohexane delta

319-86-8

1600

130

1600

130

1600

130

1600

Hexachlorocyclohexane gamma (lindane)

58-89-9

2.0

0.08

3.4

0.28

7.6

0.61

11

Hexachlorocyclopentadiene

77-47-4

3.5

0.3

3.5

0.3

3.5

0.3

NNS

Hexachloroethane

67-72-1

490

350

490

350

490

350

850

Indeno (1,2,3-cd) pyrene

193-39-5

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Isophorone

78-59-1

59000

43000

59000

43000

59000

43000

NNS

Lead (as Pb)

7439-97-1

f D

f D

f D

f D

f D

f D

f D

Manganese (as Mn)

7439-96-5

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Mercury (as Hg)

7439-97-6

2.4 D

0.01 D

2.4 D

0.01 D

2.6 D

0.2 D

5.0 D

Methoxychlor

72-43-5

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Naphthalene

91-20-3

1100

210

3200

580

3200

580

NNS

Nickel (as Ni)

7440-02-0

g D

g D

g D

g D

g D

g D

g D

Nitrate (as N)

14797-55-8

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Nitrite (as N)

14797-65-0

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Nitrate/Nitrite (as Total N)

 

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Nitrobenzene

98-95-3

1300

850

1300

850

1300

850

NNS

o-Nitrophenol

88-75-5

NNS

NNS

NNS

NNS

NNS

NNS

NNS

p-Nitrophenol

100-02-7

4100

3000

4100

3000

4100

3000

NNS

N-nitrosodimethylamine

62-75-9

NNS

NNS

NNS

NNS

NNS

NNS

NNS

N-nitrosodiphenylamine

86-30-6

2900

200

2900

200

2900

200

NNS

N-nitrosodi-n-propylamine

621-64-7

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Pentachlorophenol

87-86-5

h

h

h

h

h

h

h

Phenanthrene

85-01-8

30

6.3

30

6.3

54

6.3

NNS

Phenol

108-95-2

5100

730

7000

1000

7000

1000

180000

Polychlorinatedbiphenyls (PCBs)

1336-36-3

2.0

0.01

2.0

0.02

2.0

0.02

11

Pyrene

129-00-0

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Selenium (as Se)

7782-49-2

20 T

2.0 T

20 T

2.0 T

50 T

2.0 T

33 T

Silver (as Ag)

7440-22-4

i D

NNS

i D

NNS

i D

NNS

i D

Styrene

100-42-5

5600

370

5600

370

5600

370

NNS

Sulfides n

 

100

NNS

100

NNS

100

NNS

100

2,3,7,8-Tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD)

1746-01-6

0.01

0.005

0.01

0.005

0.12

0.01

0.1

1,1,2,2-Tetrachloroethane

79-34-5

4700

3200

4700

3200

4700

3200

NNS

Tetrachloroethylene

127-18-4

2600

280

6500

680

6500

680

15000

Thallium (as Tl)

7440-28-0

700 D

150 D

700 D

150 D

700 D

150 D

NNS

Toluene

108-88-3

8700

180

8700

180

8700

180

NNS

Toxaphene

8001-35-2

0.73

0.0002

0.73

0.02

0.73

0.02

11

1,2,4-Trichlorobenzene

120-82-1

750

130

1700

300

NNS

NNS

NNS

1,1,1-Trichloroethane

71-55-6

2600

1600

2600

1600

2600

1600

NNS

1,1,2-Trichloroethane

79-00-5

18000

12000

18000

12000

18000

12000

NNS

Trichloroethylene

79-01-6

20000

1300

20000

1300

20000

1300

NNS

2,4,6-Trichlorophenol

88-06-2

160

25

160

25

160

25

3000

2-(2,4,5-Trichlorophenoxy) proprionic acid (2,4,5-TP)

93-72-1

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Trihalomethanes, Total

 

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Uranium (as Ur)

7440-61-1

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Vinyl chloride

75-01-4

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Xylenes (Total)

1330-20-7

NNS

NNS

NNS

NNS

NNS

NNS

NNS

Zinc (as Zn)

7440-66-6

j D

 

j D

j D

j D

j D

j D

j D

Footnotes

a. The standard to protect this use is 7 million fibers (longer than 10 micrometers) per liter.

b. Values for ammonia are contained in separate tables located at the end of Appendix A.

c. Cadmium

A&Wc acute standard: (e (1.128 [ln(Hardness)] - 3.6867) ) * (1.136672-ln(hardness) * (0.041838))

A&Wc chronic standard: (e (0.7852 [ln(Hardness)] - 2.715) ) * (1.101672-ln(hardness) * (0.041838))

A&Ww acute standard: (e (1.128 [ln(Hardness)] - 3.6867) ) * (1.136672-ln(hardness) * (0.041838))

A&Ww chronic standard: (e (0.7852 [ln(Hardness)] - 2.715) ) * (1.101672-ln(hardness) * (0.041838))

A&Wedw acute standard: (e (1.128 [ln(Hardness)] - 3.6867) ) * (1.136672-ln(hardness) * (0.041838))

A&Wedw chronic standard: (e (0.7852 [ln(Hardness)] - 2.715) ) * (1.101672-ln(hardness) * (0.041838))

A&We acute standard: (e (1.128 [ln(Hardness)] - 0.9691) ) * (1.136672-ln(hardness) * (0.041838))

(See Footnote k)

d. Chromium III

A&Wc acute standard: (e (0.8190 [ln(Hardness)] + 3.7256) ) * (0.316)

A&Wc chronic standard: (e (0.8190 [ln(Hardness)] + 0.6848) ) * (0.86)

A&Ww acute standard: (e (0.8190 [ln(Hardness)] + 3.7256) ) * (0.316)

A&Ww chronic standard: (e (0.8190 [ln(Hardness)] + 0.6848) ) * (0.86)

A&Wedw acute standard: (e (0.8190 [ln(Hardness)] + 3.7256) ) * (0.316)

A&Wedw chronic standard: (e (0.8190 [ln(Hardness)] + 0.6848) ) * (0.86)

A&We acute standard: (e (0.8190 [ln(Hardness)] + 4.9361) ) * (0.316)

(See Footnote k)

e. Copper

A&Wc acute standard: (e (0.9422 [ln(Hardness)] - 1.7) ) * (0.96)

A&Wc chronic standard: (e (0.8545 [ln(Hardness)] - 1.702) ) * (0.96)

A&Ww acute standard: (e (0.9422 [ln(Hardness)] - 1.7) ) * (0.96)

A&Ww chronic standard: (e (0.8545 [ln(Hardness)] - 1.702) ) * (0.96)

A&Wedw acute standard: (e (0.9422 [ln(Hardness)] - 1.7) ) * (0.96)

A&Wedw chronic standard: (e (0.8545 [ln(Hardness)] - 1.702) ) * (0.96)

A&We acute standard: (e (0.9422 [ln(Hardness)] - 1.1514) ) * (0.96)

(See Footnote k)

f. Lead

A&Wc acute standard: (e (1.2730 [ln(Hardness)] - 1.460) ) * (1.46203-ln(hardness) * (0.145712))

A&Wc chronic standard: (e (1.2730 [ln(Hardness)] - 4.705) ) * (1.46203-ln(hardness) * (0.145712))

A&Ww acute standard: (e (1.2730 [ln(Hardness)] - 1.460) ) * (1.46203-ln(hardness) * (0.145712))

A&Ww chronic standard: (e (1.2730 [ln(Hardness)] - 4.705) ) * (1.46203-ln(hardness) * (0.145712))

A&Wedw acute standard: (e (1.2730 [ln(Hardness)] - 1.460) ) * (1.46203-ln(hardness) * (0.145712))

A&Wedw chronic standard: (e (1.2730 [ln(Hardness)] - 4.705) ) * (1.46203-ln(hardness) * (0.145712))

A&We acute standard: (e (1.2730 [ln(Hardness)] - 0.7131) ) * (1.46203-ln(hardness) * (0.145712))

(See Footnote k)

g. Nickel

A&Wc acute standard: (e (0.8460 [ln(Hardness)] + 2.255) ) * (0.998)

A&Wc chronic standard: (e (0.8460 [ln(Hardness)] + 0.0584) ) * (0.997)

A&Ww acute standard: (e (0.8460 [ln(Hardness)] + 2.255) ) * (0.998)

A&Ww chronic standard: (e (0.8460 [ln(Hardness)] + 0.0584) ) * (0.997)

A&Wedw acute standard: (e (0.8460 [ln(Hardness)] + 2.255) ) * (0.998)

A&Wedw chronic standard: (e (0.8460 [ln(Hardness)] + 0.0584) ) * (0.997)

A&We acute standard: (e (0.8460 [ln(Hardness)] + 4.4389) ) * (0.998)

(See Footnote k)

h. Pentachlorophenol

A&Wc acute standard: e (1.005 (pH) - 4.830)

A&Wc chronic standard: e (1.005 (pH) - 5.290)

A&Ww acute standard: e (1.005 (pH) - 4.830)

A&Ww chronic standard: e (1.005 (pH) - 5.290)

A&Wedw acute standard: e (1.005 (pH) - 4.830)

A&Wedw chronic standard: e (1.005 (pH) - 5.290)

A&We acute standard: e (1.005 (pH) - 3.4306)

(See Footnote l)

i. Silver

A&Wc acute standard: (e (1.72 [ln(Hardness)] - 6.52) ) * (0.85)

A&Ww acute standard: (e (1.72 [ln(Hardness)] - 6.52) ) * (0.85)

A&Wedw acute standard: (e (1.72 [ln(Hardness)] - 6.52) ) * (0.85)

A&We acute standard: (e (1.72 [ln(Hardness)] - 6.52) ) * (0.85)

(See Footnote k)

j. Zinc

A&Wc acute standard: (e (0.8473 [ln(Hardness)] + 0.884) ) * (0.978)

A&Wc chronic standard: (e (0.8473 [ln(Hardness)] + 0.884) ) * (0.978)

A&Ww acute standard: (e (0.8473 [ln(Hardness)] + 0.884) ) * 0.978)

A&Ww chronic standard: (e (0.8473 [ln(Hardness)] + 0.884) ) * (0.978)

A&Wedw acute standard: (e (0.8473 [ln(Hardness)] + 0.884) ) * (0.978)

A&Wedw chronic standard: (e (0.8473 [ln(Hardness)] + 0.884) ) * (0.978)

A&We acute standard: (e (0.8473 [ln(Hardness)] + 3.1342) ) * (0.978)

(See Footnote k)

k. Hardness, expressed as mg/L CaCO 3 , is inserted into the equation where it says "Hardness." Hardness is determined according to the following criteria:

1. If the receiving water body has an A&Wc or A&Ww designated use, then hardness is based on the hardness of the receiving water body from a sample taken at the same time that the sample for the metal is taken, except that the hardness may not exceed 400 mg / L CaCO 3 .

2. If the receiving water has an A&Wedw or A&We designated use, then the hardness is based on the hardness of the effluent from a sample taken at the same time that the sample for the metal is taken, except that the hardness may not exceed 400 mg / L CaCO 3 .

l. The pH is inserted into the equation where it says "pH". pH is determined according to the following criteria:

1. If the receiving water has an A&Wc or A&Ww designated use, then pH is based on the pH of the receiving water body from a sample taken at the same time that the sample for pentachlorophenol is taken.

2. If the receiving water body has an A&Wedw or A&We designated use, then the pH is based on the pH of the effluent from a sample taken at the same time that the sample for pentachlorophenol is taken.

m. The mathematical equations for the pH-dependent and hardness-dependent parameters represent the water quality standards. Criteria for the hardness-dependent and pH-dependent parameters have been calculated and are presented in separate tables at the end of Appendix A for the convenience of the user.

n. In lakes, the acute criteria for sulfide apply only to water samples taken from the epilimnion, or the upper layer of a lake or reservoir.

o. Bromoform, chloroform, chlorodibromomethane, and dichlorobromomethane are trihalomethanes regulated by the total trihalomethane numeric standard. The total trihalomethane standard is exceeded when the sum of these four compounds exceeds 100 µg / L.

p. The standard to protect this use is 0.003 µg/L aldrin/dieldrin.

 

µg / L- micrograms per liter

NNS - No numeric standard

D - Dissolved

T - Total recoverable

TTHM - indicates that the chemical is a trihalomethane. See Trihalomethanes, Total for DWS standard.

 

 

Table 3. Acute Water Quality Standards for dissolved Cadmium

Aquatic and Wildlife ephemeral

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

1

NA

41

24.56

81

51.39

121

79.40

161

108.18

201

137.55

241

167.40

281

197.64

321

228.24

361

259.14

2

NA

42

25.21

82

52.08

122

80.11

162

108.90

202

138.29

242

168.15

282

198.40

322

229.01

362

259.91

3

NA

43

25.86

83

52.77

123

80.82

163

109.63

203

139.03

243

168.90

283

199.17

323

229.78

363

260.69

4

NA

44

26.51

84

53.46

124

81.53

164

110.36

204

139.77

244

169.65

284

199.93

324

230.54

364

261.46

5

NA

45

27.17

85

54.15

125

82.24

165

111.09

205

140.51

245

170.40

285

200.69

325

231.31

365

262.24

6

NA

46

27.82

86

54.84

126

82.96

166

111.82

206

141.25

246

171.16

286

201.45

326

232.08

366

263.02

7

NA

47

28.48

87

55.53

127

83.67

167

112.55

207

142.00

247

171.91

287

202.21

327

232.85

367

263.79

8

NA

48

29.14

88

56.22

128

84.38

168

113.28

208

142.74

248

172.66

288

202.97

328

233.62

368

264.57

9

NA

49

29.80

89

56.92

129

85.10

169

114.01

209

143.48

249

173.41

289

203.74

329

234.39

369

265.35

10

NA

50

30.46

90

57.61

130

85.81

170

114.74

210

144.22

250

174.17

290

204.50

330

235.16

370

266.13

11

NA

51

31.12

91

58.31

131

86.53

171

115.47

211

144.97

251

174.92

291

205.26

331

235.93

371

266.90

12

NA

52

31.78

92

59.00

132

87.24

172

116.20

212

145.71

252

175.68

292

206.02

332

236.71

372

267.68

13

NA

53

32.44

93

59.70

133

87.96

173

116.93

213

146.46

253

176.43

293

206.79

333

237.48

373

268.46

14

NA

54

33.11

94

60.39

134

88.68

174

117.66

214

147.20

254

177.18

294

207.55

334

238.25

374

269.24

15

NA

55

33.77

95

61.09

135

89.39

175

118.40

215

147.94

255

177.94

295

208.31

335

239.02

375

270.02

16

NA

56

34.44

96

61.79

136

90.11

176

119.13

216

148.69

256

178.69

296

209.08

336

239.79

376

270.79

17

NA

57

35.11

97

62.48

137

90.83

177

119.86

217

149.43

257

179.45

297

209.84

337

240.56

377

271.57

18

NA

58

35.78

98

63.18

138

91.55

178

120.59

218

150.18

258

180.21

298

210.61

338

241.33

378

272.35

19

NA

59

36.45

99

63.88

139

92.26

179

121.33

219

150.93

259

180.96

299

211.37

339

242.11

379

273.13

20

NA

60

37.12

100

64.58

140

92.98

180

122.06

220

151.67

260

181.72

300

212.13

340

242.88

380

273.91

21

NA

61

37.79

101

65.28

141

93.70

181

122.80

221

152.42

261

182.47

301

212.90

341

243.65

381

274.69

22

NA

62

38.46

102

65.98

142

94.42

182

123.53

222

153.16

262

183.23

302

213.66

342

244.42

382

275.47

23

NA

63

39.13

103

66.68

143

95.14

183

124.27

223

153.91

263

183.99

303

214.43

343

245.20

383

276.25

24

NA

64

39.81

104

67.38

144

95.86

184

125.00

224

154.66

264

184.74

304

215.20

344

245.97

384

277.03

25

14.35

65

40.48

105

68.09

145

96.58

185

125.74

225

155.40

265

185.50

305

215.96

345

246.74

385

277.81

26

14.98

66

41.16

106

68.79

146

97.31

186

126.47

226

156.15

266

186.26

306

216.73

346

247.51

386

278.59

27

15.60

67

41.84

107

69.49

147

98.03

187

127.21

227

156.90

267

187.01

307

217.49

347

248.29

387

279.37

28

16.23

68

42.51

108

70.20

148

98.75

188

127.95

228

157.65

268

187.77

308

218.26

348

249.06

388

280.15

29

16.86

69

43.19

109

70.90

149

99.47

189

128.68

229

158.40

269

188.53

309

219.03

349

249.84

389

280.93

30

17.49

70

43.87

110

71.61

150

100.20

190

129.42

230

159.14

270

189.29

310

219.79

350

250.61

390

281.71

31

18.13

71

44.55

111

72.31

151

100.92

191

130.16

231

159.89

271

190.05

311

220.56

351

251.38

391

282.49

32

18.76

72

45.23

112

73.02

152

101.64

192

130.89

232

160.64

272

190.81

312

221.33

352

252.16

392

283.27

33

19.40

73

45.91

113

73.72

153

102.37

193

131.63

233

161.39

273

191.56

313

222.09

353

252.93

393

284.05

34

20.04

74

46.60

114

74.43

154

103.09

194

132.37

234

162.14

274

192.32

314

222.86

354

253.71

394

284.83

35

20.68

75

47.28

115

75.14

155

103.82

195

133.11

235

162.89

275

193.08

315

223.63

355

254.48

395

285.61

36

21.32

76

47.96

116

75.85

156

104.54

196

133.85

236

163.64

276

193.84

316

224.40

356

255.26

396

286.40

37

21.97

77

48.65

117

76.56

157

105.27

197

134.59

237

164.39

277

194.60

317

225.16

357

256.03

397

287.18

38

22.61

78

49.33

118

77.27

158

106.00

198

135.33

238

165.14

278

195.36

318

225.93

358

256.81

398

287.96

39

23.26

79

50.02

119

77.97

159

106.72

199

136.07

239

165.89

279

196.12

319

226.70

359

257.58

399

288.74

40

23.91

80

50.71

120

78.68

160

107.45

200

136.81

240

166.64

280

196.88

320

227.47

360

258.36

400

289.52

 

Table 4. Acute Water Quality Standards for dissolved Cadmium

Aquatic and Wildlife coldwater, warmwater, and edw

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

Hard.

Std.

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

mg/L

ug/L

1

NA

41

1.62

81

3.39

121

5.24

161

7.14

201

9.08

241

11.05

281

13.05

321

15.07

361

17.11

2

NA

42

1.66

82

3.44

122

5.29

162

7.19

202

9.13

242

11.10

282

13.10

322

15.12

362

17.16

3

NA

43

1.71

83

3.48

123

5.34

163

7.24

203

9.18

243

11.15

283

13.15

323

15.17

363

17.21

4

NA

44

1.75

84

3.53

124

5.38

164

7.29

204

9.23

244

11.20

284

13.20

324

15.22

364

17.27

5

NA

45

1.79

85

3.58

125

5.43

165

7.34

205

9.28

245

11.25

285

13.25

325

15.27

365

17.32

6

NA

46

1.84

86

3.62

126

5.48

166

7.38

206

9.33

246

11.30

286

13.30

326

15.33

366

17.37

7

NA

47

1.88

87

3.67

127

5.52

167

7.43

207

9.38

247

11.35

287

13.35

327

15.38

367

17.42

8

NA

48

1.92

88

3.71

128

5.57

168

7.48

208

9.43

248

11.40

288

13.40

328

15.43

368

17.47

9

NA

49

1.97

89

3.76

129

5.62

169

7.53

209

9.47

249

11.45

289

13.45

329

15.48

369

17.52

10

NA

50

2.01

90

3.80

130

5.67

170

7.58

210

9.52

250

11.50

290

13.50

330

15.53

370

17.57

11

NA

51

2.05

91

3.85

131

5.71

171

7.62

211

9.57

251

11.55

291

13.55

331

15.58

371

17.62

12

NA

52

2.10

92

3.90

132

5.76

172

7.67

212

9.62

252

11.60

292

13.60

332

15.63

372

17.68

13

NA

53

2.14

93

3.94

133

5.81

173

7.72

213

9.67

253

11.65

293

13.65

333

15.68

373

17.73

14

NA

54

2.19

94

3.99

134

5.86

174

7.77

214

9.72

254

11.70

294

13.71

334

15.73

374

17.78

15

NA

55

2.23

95

4.03

135

5.90

175

7.82

215

9.77

255

11.75

295

13.76

335

15.78

375

17.83

16

NA

56

2.27

96

4.08

136

5.95

176

7.87

216

9.82

256

11.80

296

13.81

336

15.83

376

17.88

17

NA

57

2.32

97

4.13

137

6.00

177

7.91

217

9.87

257

11.85

297

13.86

337

15.89

377

17.93

18

NA

58

2.36

98

4.17

138

6.05

178

7.96

218

9.92

258

11.90

298

13.91

338

15.94

378

17.98

19

NA

59

2.41

99

4.22

139

6.09

179

8.01

219

9.97

259

11.95

299

13.96

339

15.99

379

18.04

20

NA

60

2.45

100

4.26

140

6.14

180

8.06

220

10.02

260

12.00

300

14.01

340

16.04

380

18.09

21

NA

61

2.50

101

4.31

141

6.19

181

8.11

221

10.06

261

12.05

301

14.06

341

16.09

381

18.14

22

NA

62

2.54

102

4.36

142

6.24

182

8.16

222

10.11

262

12.10

302

14.11

342

16.14

382

18.19

23

NA

63

2.58

103

4.40

143

6.28

183

8.21

223

10.16

263

12.15

303

14.16

343

16.19

383

18.24

24

NA

64

2.63

104

4.45

144

6.33

184

8.25

224

10.21

264

12.20

304

14.21

344

16.24

384

18.29